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Phonon-Induced Population Dynamics and Intersystem Crossing in Nitrogen-Vacancy Centers

MetadataDetails
Publication Date2015-04-08
JournalPhysical Review Letters
AuthorsMichael Goldman, Alp Sipahigil, Marcus W. Doherty, Norman Y. Yao, Steven Bennett
InstitutionsElement Six (United Kingdom), Harvard University
Citations175

We report direct measurement of population dynamics in the excited state manifold of a nitrogen-vacancy (NV) center in diamond. We quantify the phonon-induced mixing rate and demonstrate that it can be completely suppressed at low temperatures. Further, we measure the intersystem crossing (ISC) rate for different excited states and develop a theoretical model that unifies the phonon-induced mixing and ISC mechanisms. We find that our model is in excellent agreement with experiment and that it can be used to predict unknown elements of the NV center’s electronic structure. We discuss the model’s implications for enhancing the NV center’s performance as a room-temperature sensor.