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Defect engineering of diamond cathodes for high temperature solar cells

MetadataDetails
Publication Date2015-06-01
AuthorsA. Bellucci, P. Calvani, M. Girolami, D.M. Trucchi
InstitutionsSapienza University of Rome, Institute of Structure of Matter
Citations12

A cathode structure for photon-enhanced thermionic emission was designed for high temperature energy conversion in solar concentrating systems. Surface-hydrogenated diamond is one of the few semiconductors to show negative electron affinity and a work function as low as 1.7 eV if nitrogen-doped, that is connected to a significant thermionic emission at moderate temperatures (up to 800 °C). But diamond is transparent to solar radiation, consequently advanced techniques for preparing an efficient sunlight absorbing diamond are discussed.