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Preparation of copper oxide modified boron-doped diamond electrodes and its preliminary study for CO2 reduction

MetadataDetails
Publication Date2017-04-01
JournalIOP Conference Series Materials Science and Engineering
AuthorsN Y Yetri, Tribidasari A. Ivandini, Jarnuzi Gunlazuardi
InstitutionsUniversity of Indonesia
Citations7

Preparation of boron-doped diamond (BDD) modified with Cu2O (Cu2O-BDD) electrodes was conducted to study the electrochemical reduction of CO2. The electrodes were prepared by electrochemical reduction using a solution containing 1mM Cu(CH3COO)2 and 0.1 M CH3COONa (1:1) at pH 5.7 for 60 s. The electrodeposition of Cu2O at BDD surface was performed by chronoamperometry technique at āˆ’0.4 V (vs Ag/AgCl). SEM-EDS and XPS were utilized to characterize the electrodes. At Cu2O-BDD electrodes, cyclic voltammetry of dissolved CO2 in 0.1 M NaCl solution exhibited a reduction peak at around āˆ’1.3 V (vs Ag/AgCl), indicated the possibility for application in electrochemical reduction of CO2.