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Electrooxidation of Diclofenac in Synthetic Pharmaceutical Wastewater Using an Electrochemical Reactor Equipped with a Boron Doped Diamond Electrode

MetadataDetails
Publication Date2017-10-12
JournalJournal of the Mexican Chemical Society
AuthorsGabriela Coria, JosƩ L. Nava, Gilberto CarreƱo
InstitutionsUniversidad de Guanajuato
Citations12

This paper deals with the degradation of diclofenac by electrochemical oxidation in NaClO4 medium at neutral pH using a FM01-LC reactor equipped with a boron doped diamond electrode (BDD). Microelectrolysis studies were carried out to find the current density domain where hydroxyl radical (•OH) formation is favored, 10 ≤ j ≤ 20 mA cm-2. Electrolysis experiments at mean linear flow velocities of 14.6 ≤ u ≤ 58.4 cm s-1 were performed. The experimental set-up achieved 100% diclofenac mineralization with 78% current efficiency and energy consumption of 2.54 kWh m-3 at j = 15 mA cm-2 and u=29.2 cm s-1.