Electrooxidation of Diclofenac in Synthetic Pharmaceutical Wastewater Using an Electrochemical Reactor Equipped with a Boron Doped Diamond Electrode
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2017-10-12 |
| Journal | Journal of the Mexican Chemical Society |
| Authors | Gabriela Coria, JosƩ L. Nava, Gilberto CarreƱo |
| Institutions | Universidad de Guanajuato |
| Citations | 12 |
Abstract
Section titled āAbstractāThis paper deals with the degradation of diclofenac by electrochemical oxidation in NaClO4 medium at neutral pH using a FM01-LC reactor equipped with a boron doped diamond electrode (BDD). Microelectrolysis studies were carried out to find the current density domain where hydroxyl radical (ā¢OH) formation is favored, 10 ⤠j ⤠20 mA cm-2. Electrolysis experiments at mean linear flow velocities of 14.6 ⤠u ⤠58.4 cm s-1 were performed. The experimental set-up achieved 100% diclofenac mineralization with 78% current efficiency and energy consumption of 2.54 kWh m-3 at j = 15 mA cm-2 and u=29.2 cm s-1.