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Hypochlorous Acid Sensor using Boron-Doped Diamond Electrode in Physiological pH Solution

MetadataDetails
Publication Date2018-12-01
AuthorsNadiatus Silmi, Tribidasari A. Ivandini, Asijati W. Endang
InstitutionsUniversity of Indonesia
Citations2

Electrochemical behavior of hypochlorous acid (HClO) have been studied at boron-doped diamond (BDD) electrodes in physiological pH solution. The electrochemical measurements were performed in one-compartment electrochemical cell using cyclic voltammetry technique. A solution of 0.5 M phosphate buffer solution has been selected as the supporting electrolyte. Cyclic voltammograms of NaClO standard solutions showed the best response at optimum pH of 6.6 at the potential reduction of +0.1 V. Linear calibration curve ( R <sup xmlns:mml=ā€œhttp://www.w3.org/1998/Math/MathMLā€ xmlns:xlink=ā€œhttp://www.w3.org/1999/xlinkā€&gt;2&lt;/sup> =0.9953) can be achieved at a NaClO concentration range from 1.68 to 5.86 mM with an estimated limit of detection (LOD) of 0.46 mM.

  1. 2017 - Development of electrolyte-free ozone sensors using boron-doped diamond electrodes Anal
  2. 2009 - Disinfection efficacy of Medilox Super-oxidized water with neutral pH