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Electrochemical study of nickel-cobalt deposited on boron-doped diamond as working electrodes for urea fuel cells

MetadataDetails
Publication Date2019-05-07
JournalIOP Conference Series Materials Science and Engineering
AuthorsYulia Mariana Tesa Ayudia Putri, Jarnuzi Gunlazuardi, Tribidasari A. Ivandini
InstitutionsUniversity of Indonesia
Citations9

Urea as one of the most abundant compounds that can be used as a fuel in fuel cells. It contains a nitrogen-hydrogen bond that can easily be broken by electrochemical processes to produce two molecules of hydrogen. The hydrogen released can generate electricity as in a fuel cell. In this research, boron-doped diamond (BDD) was modified using nickel and/or cobalt electrodeposition to provide Ni-Co-BDD, Ni-BDD, and Co-BDD working electrodes for enhanced urea electro-oxidation. The highest power density and potential was achieved using Ni-Co-BDD (96.4 mW cmāˆ’2 and 0.92 V, respectively), while the highest current density was achieved using Co-BDD (165.34 mA cmāˆ’2). Overall, the results indicate that the best and most stable electrode for fuel cells is that based on Ni-Co-BDD.