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Electrochemical Oxidation of Two Phenolic Compounds - Evaluation of Kinetics and Energy Consumption

MetadataDetails
Publication Date2019-10-25
JournalECS Transactions
AuthorsCarlos Javier Escudero, Marı́a J. Rivero, Inmaculada Ortíz
InstitutionsUniversidad de Cantabria, Universidad Autónoma de Guadalajara
Citations2

Bisphenol A (BPA) and p-cresol are two phenolic compounds present in industrial wastewater and they are harmful to the environment. Electrochemical oxidation is a technology that has the ease of coupling to other treatment systems and is environmentally friendly. In this study, electrochemical oxidation of 100 mg/L of BPA and 50 mg/L of p-cresol were tasted using Boron Doped diamond (BDD) anodes. The results aim that the pseudo-first order kinetic constants (k) had the same order of magnitude for both compounds. Slightly higher values of k were obtained when using a J of 250 A/m2 than other conditions, removing the pollutants in less than 120 min; while the mineralization was completed around 240 and 210 min, respectively. To compare the energy consumption, the parameter Electrical Energy per Order was used, obtaining that to eliminate 90% of the compounds it is required between 6-8 kWĀ·h/m3Ā·order and 60 kWĀ·h/m3Ā·order for the mineralization.