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Copper-nickel-modified Boron-doped Diamond Electrode for CO2 Electrochemical Reduction Application - A Preliminary Study

MetadataDetails
Publication Date2019-12-20
JournalMakara Journal of Science
AuthorsPrastika Krisma Jiwanti, Rani Puspitasar Aritonang, Imam Abdullah, Yasuaki Einaga, Tribidasari A. Ivandini
InstitutionsKeio University, Airlangga University
Citations18

CO2 electrochemical reduction (CO2ER) activity is known to be influenced by electrode materials. In this study, we report the fabrication of a copper-nickel-modified boron-doped diamond (CuNi-BDD) electrode using wet chemical seeding and electrodeposition. Annealing was performed to improve the stability of the modified electrode during elec-trolysis. Characterization of the modified BDD electrodes shows successful deposition without damage to the surface of the BDD support material. CO2ER was conducted with the CuNi-BDD electrode, which produces various important products including methanol, formic acid, CO, and CH4. Additionally, a different applied potential affected the product distribution. CO2ER was also conducted on the surfaces of Cu-BDD and Ni-BDD electrodes for comparison.