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Heavy boron doping in superconducting carbon materials

MetadataDetails
Publication Date2020-05-04
JournalPhysical Review Materials
AuthorsYuki Sakai, James R. Chelikowsky, Marvin L. Cohen
InstitutionsThe University of Texas at Austin, Lawrence Berkeley National Laboratory
Citations8

Here we examine physical properties of heavily boron-doped sp<sup>3</sup>-hybridized carbon allotropes: cubic diamond, hexagonal diamond, and body centered tetragonal C<sub>4</sub>. The structural similarity between cubic diamond and hexagonal diamond leads to similar responses to substitutional boron doping. On the other hand, body centered tetragonal C<sub>4</sub> exhibits distinct structural and electronic properties because of its characteristic structure. Our study also shows that the superconducting transition temperatures up to 60 K are possible in heavily doped carbon materials despite their various atomistic structures.