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Electrochemical Modulation of Odorant Molecule - A Study of p-cresol

MetadataDetails
Publication Date2020-09-16
JournalJournal of The Electrochemical Society
AuthorsMariana M. Vasquez, Edgard Ngaboyamahina
InstitutionsDuke University
Citations1

p-Cresol modulation was for the first time evaluated as an alternative option for odor control in sanitation facilities. Results indicate that the oxidation of p-cresol can generate 4-hydroxybenzaldehyde (4-HB), a molecule with a sweet-woody odor, following the introduction of chloride ions into the supporting electrolyte. In an attempt to impede electrode fouling, pulsed chronoamperometry (CA) was implemented and resulted in ∼10% higher p-cresol removal compared to CA at constant potential. Boron doped diamond (BDD) was also explored as an alternative working electrode. p-Cresol oxidation on the diamond surface resulted in higher removal percentages, but the desired oxidation product was not detected by Liquid chromatography-mass spectrometry (LC-MS) likely due to complete combustion.

  1. 2005 - Analytical approaches to vanilla quality and authentication
  2. 2009 - A thesis submitted to the faculty of the graduate school of the university of colorado at boulder