Chemical Mechanical Polishing of Single-Crystalline Diamond Epitaxial Layers for Electronics Applications
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2024-03-29 |
| Journal | IEEE Transactions on Semiconductor Manufacturing |
| Authors | Aaron Hardy, Matthias Muehle, Cristian J. Herrera-Rodriguez, Michael Becker, Edward Drown |
| Institutions | Michigan State University, Fraunhofer USA |
| Citations | 6 |
Abstract
Section titled āAbstractāFor single crystal diamond (SCD) to gain practical use in technical applications including solid state electronics, thin (<1 Ī¼m), doped epitaxial SCD layers with very low (<1 nm) surface roughness are required. Conventional SCD chemical mechanical polishing (CMP) processes are insufficient to meet the requirements of such applications because the material removal rate (MRR) is often characterized inappropriately, and the material removal uniformity is seldom considered. In this study, chemical vapor deposition (CVD) growth of two lightly boron doped (p-) epilayers was performed on 3misoriented (100) high pressure high temperature substrates of 4.5 x 4.5 mm2 area. A subsequent 8-hour oxidative CMP process utilizing potassium permanganate and a novel self-leveling holder design decreased the average surface roughness from 3.83 nm and 1.57 nm to 0.20 nm and 0.16 nm for the two samples, respectively. MRRs were determined by evaluating five circular wear monitor structures in each sample by atomic force microscopy before and after the CMP process. The average MRRs were found to be 38.6 nm/hr and 37.3 nm/hr for the two samples. The purpose of this study is to demonstrate a CMP process suitable for polishing thin SCD epilayers to meet the needs of solid-state electronics applications.