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Revealing the Adsorption Behavior of Nitrogen Reduction Reaction on Strained Ti2CO2 by a Spin‐Polarized d‐band Center Model (Small 9/2024)

MetadataDetails
Publication Date2024-03-01
JournalSmall
AuthorsYaqin Zhang, Yuhang Wang, Ninggui Ma, Bochun Liang, Yu Xiong
InstitutionsCity University of Hong Kong

Nitrogen Reduction Reaction In article number 2306840, Jun Fan and co-workers showed that tensile strain tuning the oxidation states of Ti and favoring O-vacancy formation in Ti2CO2 enhances electrochemical dinitrogen reduction. The downshift of d-band center leads to unique adsorption behaviors of N-containing intermediates, which is elucidated by a spin-polarized d-band center model.