Creation, Control, and Modeling of NV Centers in Nanodiamonds
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2024-07-01 |
| Journal | Advanced Functional Materials |
| Authors | Pietro AprĆ , Nour Hanne Amine, Adam Britel, Sofia Sturari, Veronica Varzi |
| Institutions | University of Turin, Torino e-district |
| Citations | 10 |
Abstract
Section titled āAbstractāAbstract Sensing based on NitrogenāVacancy (NV) centers in nanodiamonds (NDs) represents a potentially groundbreaking technology with broad applications. Nevertheless, the optimization of their quantumāoptical properties is still a challenging issue. The present work aims at enhancing and controlling NV centers optical properties in NDs by combining their surface chemistry tuning and proton beam irradiation. Systematic thermal oxidations are carried out to study the evolution of surface chemical groups (IR spectroscopy), as well as their influence on optical properties (photoluminescence spectroscopy, PL decay measurements). Proton irradiation is performed by exploring a wide range of fluences (10 14 - 10 17 cm ā2 ) in order to precisely control the amount of NV centers, thus defining the conditions that maximize their creation and emission intensity. In addition, NV centers charge state control is achieved by assessing NV ā /NV 0 ratio upon different surface termination tuning and NV centers amount. Finally, a novel predictive mathematical model is developed, allowing for the evaluation of the efficiencies of the formation of both NV ā and NV 0 . Although the model is tested in the specific case study with proton irradiated NDs, it offers a broad applicability, thus representing a key landmark in the prediction of the outcome of ionābeamābased color centers generation in diamond.