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Electrochemically Catalytic Activity of Boron-doped Diamond for I<sup>−</sup>/I<sup>0</sup> Redox Couple

MetadataDetails
Publication Date2015-01-01
JournalElectrochemistry
AuthorsJin Kawakita, Yasuo Hashimoto Shinoda, Yukihiro Sakamoto
InstitutionsNational Institute for Materials Science, Chiba Institute of Technology
Citations4

Boron-doped diamond (BDD) is promising as electrocatalyst for alternative material to platinum (Pt) because of its superior chemical stability. Electrochemically catalytic activity of BDD on the redox couple of Iāˆ’/I0 was studied by using the electrochemical method. It showed the parabolic dependence on the doping level of boron in diamond and the maximum value was 0.94 µA/cm2 in terms of the exchanging current density. This value is slightly higher than graphite and smaller than Pt. Additional surface modification of BDD could improve the catalytic activity.