Skip to content

Nanometer-scale exchange interactions between spin centers in diamond

MetadataDetails
Publication Date2016-06-15
JournalPhysical review. B./Physical review. B
AuthorsV. R. Kortan, CĂŒneyt ƞahin, Michael E. FlattĂ©
InstitutionsUniversity of Iowa
Citations8

Exchange interactions between isolated pairs of spin centers in diamond have\nbeen calculated, based on an accurate atomistic electronic structure for\ndiamond and any impurity atoms, for spin-center separations up to 2nm. The\nexchange interactions exceed dipolar interactions for spin center separations\nless than 3nm. NV$^-$ spin centers, which are extended defects, interact very\ndifferently depending on the relative orientations of the symmetry axis of the\nspin center and the radius vector connecting the pair. Exchange interactions\nbetween transition-metal dopants behave similarly to those of NV$^-$ centers.\nThe Mn\---Mn exchange interaction decays with a much longer length scale than\nthe Cr\---Cr and Ni\---Ni exchange interactions, exceeding dipolar interactions\nfor Mn\---Mn separations less than 5~nm. Calculations of these highly\nanisotropic and spin-center-dependent interactions provide the potential for\ndesign of the spin-spin interactions for novel nanomagnetic structures.\n