Influence of optically active defects on thermal conductivity of polycrystalline diamond
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2017-09-22 |
| Journal | The European Physical Journal Applied Physics |
| Authors | Qinyu Kong, Alvarado Tarun, C.M. Yap, Siwei Xiao, Kun Liang |
| Institutions | Nanyang Technological University |
| Citations | 1 |
Abstract
Section titled āAbstractāWe systematically studied the influence of optically active defects on thermal conductivity for polycrystalline diamonds (PCDs) with different colour, crystalline quality and impurity concentrations. The thermal conductivities of PCDs on the growth (top) and nucleation (bottom) surfaces were characterized with 3 Ļ technique. It is found that the bottom surface shows lower thermal conductivity as compared to the top surface. This could be due to the higher defect density in the bottom surface. Defects analyzed includes non-diamond carbon phase, C-H stretching vibration, Si vacancy, and substitutional nitrogen (Ns 0 ). Our results suggest that, for the top surface, the heat transport is mainly controlled by the concentration of Ns 0 . For the bottom surface, non-diamond carbon phase, Si vacancy, C-H stretch and Ns 0 defects all lead to an obvious reduction in the thermal conductivity. Most importantly, we derived a well fitted equation that estimates the thermal conductivity by optical transmittance, and the equation was demonstrated to be valid at any wavelength in visible region.