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Intrinsic stress modulation in diamond like carbon films with incorporation of gold nanoparticles by PLA

MetadataDetails
Publication Date2018-01-01
JournalAIP conference proceedings
AuthorsMadhusmita Panda, R. Krishnan, Nanda Gopala Krishna, Kishore K. Madapu, M. Kamruddin
InstitutionsHomi Bhabha National Institute, Indira Gandhi Centre for Atomic Research
Citations4

Intrinsic stress modulation in the diamond-like carbon (DLC) coatings with incorporation of gold nanoparticles was studied qualitatively from Raman shift. The films were deposited on Si (1 0 0) substrates by using Pulsed laser ablation (PLA) of pure pyrolytic graphite target and with a gold foil on it. Films compositional and chemical behavior was studied by X-ray photoelectron spectroscopy (XPS) and Visible Raman spectroscopy, respectively. The sp3 content obtained from XPS shows dramatic variation in DLC, DLC-Au(100), DLC-Au(200) and DLC-Au(300) as 39%, 41%, 47% and 66% with various gold contentsas 0%, 12%, 7.3% and 4.7%, respectively. The Raman spectra of DLC/Au films showed G-peak shift towards lower wavenumber indicating the reduction of intrinsic stress (internal compressive stress). The sp2, sp3 fraction in the films are also determined from FWHM (G-Peak).