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Gas Composition Influence on the Properties of Boron-Doped Diamond Films Deposited on the Fused Silica

MetadataDetails
Publication Date2018-06-01
JournalMaterials Science-Poland
AuthorsBartłomiej Dec, Mateusz Ficek, Michał Rycewicz, Łukasz Macewicz, Marcin Gnyba
InstitutionsPolish Academy of Sciences, Institute of Fluid Flow-Machinery
Citations11

Abstract The main subject of this study are molecular structures and optical properties of boron-doped diamond films with [B]/[C] ppm ratio between 1000 and 10 000, fabricated in two molar ratios of CH 4 -H 2 mixture (1 % and 4 %). Boron-doped diamond (BDD) film on the fused silica was presented as a conductive coating for optical and electronic purposes. The scanning electron microscopy images showed homogenous and polycrystalline surface morphology. The Raman spectroscopy confirmed the growth of sp 3 diamond phase and sp 2 carbon phase, both regular and amorphous, on the grain boundaries, as well as the efficiency of boron doping. The sp 3 /sp 2 ratio was calculated using the Raman spectra deconvolution method. A high refractive index (in a range of 2.0 to 2.4 at λ= 550 nm) was achieved for BDD films deposited at 700 °C. The values of extinction coefficient were below 1.4 at λ= 550 nm, indicating low absorption of the film