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Thermal expansion coefficients of high thermal conducting BAs and BP materials

MetadataDetails
Publication Date2019-07-01
JournalApplied Physics Letters
AuthorsSheng Li, Keith M. Taddei, Xiqu Wang, Hanlin WU, Joerg Neuefeind
InstitutionsThe University of Texas at Dallas, University of Houston
Citations19

Recently reported very high thermal conductivities in cubic boron arsenide (BAs) and boron phosphide (BP) crystals could potentially provide a revolutionary solution in the thermal management of high power density devices. To fully facilitate such an application, the compatible coefficient of thermal expansion (CTE) between the heat spreader and the device substrate, in order to minimize the thermal stress, needs to be considered. Here, we report our experimental CTE studies of BAs and BP in the temperature range from 100 K to 1150 K, through a combination of X-ray single crystal diffraction and neutron powder diffraction. We demonstrated that the room temperature CTEs, 3.6 ± 0.15 Ɨ 10āˆ’6/K for BAs and 3.2 ± 0.2 Ɨ 10āˆ’6/K for BP, are more compatible with most of the semiconductors including Si and GaAs, in comparison with diamond, and thus could be better candidates for the future heat spreader materials in power electronic devices.

  1. 2011 - Advanced Materials for Thermal Management of Electronic Packaging