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Specific Features of Spectrally Resolved Thermoluminescence in UV-Irradiated Aluminum Nitride Microcrystals

MetadataDetails
Publication Date2020-09-01
JournalOptics and Spectroscopy
AuthorsD.M. Spiridonov, Š”. Š’. Чайкин, N. A. Martemyanov, A. S. Vokhmintsev, I. A. Weinstein
InstitutionsRussian Academy of Sciences, Institute of Metallurgy
Citations4

The mechanisms of photo- and thermoluminescence processes in cation-deficient submicron AlN crystals after UV excitation are studied. The observed emission spectra represent a superposition of bands peaking at 3.0 and 2.5 eV. These spectral features are related to electronic transitions with participation of ON impurity centers and oxygen-vacancy centers of the VAl-ON type. According to a quantitative analysis within the general-order kinetics formalism, charge carrier trapping centers based on nitrogen vacancies VN have an activation energy of 0.45 eV and are responsible for the formation of a thermally activated peak at a temperature of 345 K.