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6CCVD Research

Electrochemical preparation of defect-engineered titania - Bulk doping versus surface contamination

At a Glance

Section titled “At a Glance”
MetadataDetails
Publication Date2020-10-26
JournalApplied Surface Science
AuthorsRobert BrĂŒninghoff, Ainoa Paradelo RodrĂ­guez, Ronald P. H. Jong, Jacobus M. Sturm, U. Breuer
InstitutionsForschungszentrum JĂŒlich, Magneto Special Anodes (Netherlands)
Citations7

Abstract

Section titled “Abstract”

Defect-engineered or substoichiometric TiOx is of interest for use in photo- and electrocatalytic processes both as active material and catalyst support. Electrochemical doping of TiO2 via cathodic polarization is an appealing preparation method and frequently employed. Here, we explored the electrochemical preparation of TiOx in an undivided cell using iridium-based (iridium mixed-metal-oxide) and boron doped diamond (BDD) counter electrodes. Cyclic voltammetry and impedance spectroscopy revealed superior charge transfer properties of crystalline TiOx electrodes prepared with BDD (TiOx-BDD). It is shown that the electrochemical properties correlate well with intensities of the H-signals determined using Time of Flight - Secondary Ion Mass Spectrometry (ToF-SIMS). Thus, it is concluded that electrochemical preparation using BDD causes favourable H+ intercalation and/or H diffusion into the sub-surface layers of TiOx. Our extensive analysis using a combination of electrochemical and surface characterization (LEIS and XPS) techniques, additionally suggests that cathodic deposition of Ir, originating from the Ir-based counter electrode, present in sub-ppm concentrations only results in less-efficient doping. Instead in the presence of sub-ppm level Ir contamination hydrogen evolution is favoured during cathodic polarization. The results presented within this study highlight the necessity to use inherently stable counter electrodes for electrochemical preparation and reveal the pronounced influence of trace contamination in electrochemistry in general and the doping mechanism of TiOx electrodes in particular.

Tech Support

Section titled “Tech Support”

Original Source

Section titled “Original Source”

References

Section titled “References”
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