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Preferential Placement of Aligned Nitrogen Vacancy Centers in Chemical Vapor Deposition Overgrown Diamond Microstructures

MetadataDetails
Publication Date2021-09-09
Journalphysica status solidi (RRL) - Rapid Research Letters
AuthorsArne Götze, Nico Striegler, Alastair Marshall, Philipp Neumann, Christian Giese
InstitutionsOmniVision Technologies (Germany), Fraunhofer Institute for Applied Solid State Physics
Citations8

The usefulness of nitrogen vacancy (NV) centers in diamond is augmented by a low defect and impurity density in the surrounding host material, and applications benefit from the ability to control the position of the NV centers. Herein, a process to create NV centers on single‐crystalline diamond microstructures by chemical vapor deposition (CVD) is presented. Pyramidal structures with {111} side facets are formed during the intrinsic overgrowth of dry chemically etched cylindrical pillars on a substrate with {100} surface orientation. A thin nitrogen‐doped epitaxial layer is deposited on top of the pyramids resulting in the creation of NV centers exclusively on the {111} pyramid side faces. Optically detected magnetic resonance (ODMR) and spin echo measurements reveal preferential alignment of the NV centers in a single {111} direction and a time of . The time of the NV centers is limited by the surrounding substitutional nitrogen (P1 center) concentration of . A low density of other paramagnetic spin noise is detected by double‐electron electron resonance (DEER) measurements.