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Effect of a-MoS2 and a-MoS3 nanophases on tribological properties of nanocomposite coatings containing diamond-like carbon

MetadataDetails
Publication Date2022-01-01
JournalStrengthening Technologies and Coatings
AuthorsD.V. Fominsky, M.V. Demin, M.D. Gritskevich, V.A. Kasyanenko, V.Yu. Fominsky

Using the modes of reactive and vacuum pulsed laser deposition, nanocomposite coatings consisting of alternating layers of amorphous molybdenum sulfide (a-MoSx) and diamond-like carbon (a-C) were created. For solid lubricating layers, the compositions a-MoS2 and a-MoS3 were chosen. The study of tribological properties was carried out according to the method of sliding a ball on a disk in very different environmental conditions: humid air, dry air at +25 °C and -100 °C. A significant effect of the composition of the a-MoSx phase on the friction and wear of the nanocomposite coatings in humid air and at low temperature has been established. The use of the a-MoS3 polymer-like phase provided better antifriction properties and increased durability of the coatings. In dry air, the coatings with the a-MoS2 nanophase exhibited a lower coefficient of friction than those with a-MoS3 with approximately the same wear resistance between them. The results of the study of tribo-induced changes in coatings by micro-Raman spectroscopy are presented.