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Template-Assisted Self-Assembly of Fluorescent Nanodiamonds for Scalable Quantum Technologies

MetadataDetails
Publication Date2022-01-13
JournalACS Nano
AuthorsHenry J. Shulevitz, Tzu‐Yung Huang, Jun Xu, Steven J. Neuhaus, Raj N. Patel
InstitutionsUniversity of Pennsylvania
Citations36
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Milled nanodiamonds containing nitrogen-vacancy (NV) centers are nanoscale quantum sensors that form colloidal dispersions. However, variations in their size, shape, and surface chemistry limit the ability to position individual nanodiamonds and statistically study properties that affect their optical and quantum characteristics. Here, we present a scalable strategy to form ordered arrays of nanodiamonds using capillary-driven, template-assisted self-assembly. We demonstrate the precise spatial arrangement of isolated nanodiamonds with diameters below 50 nm across millimeter-scale areas. Measurements of over 200 assembled nanodiamonds yield a statistical understanding of their structural, optical, and quantum properties. The NV centers’ spin and charge properties are uncorrelated with nanodiamond size but rather are consistent with heterogeneity in their nanoscale environment.