Quantitative Evaluations on Ozone Evolution Electrocatalysts by Scanning Electrochemical Microscopy for Oxidative Water Treatment
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2022-10-17 |
| Journal | Environmental Science & Technology |
| Authors | Woonghee Lee, Seok Kim, Kangwoo Cho |
| Institutions | Advanced Institute of Convergence Technology, Yonsei University |
| Citations | 9 |
Abstract
Section titled āAbstractāThis study valorized scanning electrochemical microscopy (SECM) for the detection of dissolved O<sub>3</sub>, which is increasingly in demand for water treatment. Au ultramicroelectrodes biased at 0.62 V RHE provided superior activity and selectivity for O<sub>3</sub> reduction, compared to Pt analogues. It allowed quantitative <i>in situ</i> interrogation of ozone evolution reaction (OZER) electrocatalysts with unprecedented estimations on the OZER overpotential. The difference in onset potentials between the OZER and the competing oxygen evolution reaction (OER) primarily accounted for the OZER current efficiency (CE) on boron-doped diamond (BDD, 1.4% at 10 mA cm<sup>-2</sup> in 0.5 M H<sub>2</sub>SO<sub>4</sub>), Ni-Sb-doped SnO<sub>2</sub> (NSS, 10.8%), and SiO<sub><i>x</i></sub>-coated NSS (NSS/SiO<sub><i>x</i></sub>, 34.4%). SECM areal scans in tandem with elemental mapping perspicuously visualized the improved OZER activity by the SiO<sub><i>x</i></sub> overlayer on NSS. A shift in the charge transfer coefficient further rationalized the elevated OZER selectivity on NSS/SiO<sub><i>x</i></sub>, in association with the weakened Sn-O bond strength confirmed by valence band X-ray photoelectron spectra. The invigorated OZER on NSS/SiO<sub><i>x</i></sub> effectively accelerated the degradation of a model aqueous pollutant (4-chlorophenol).