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Anodic Fluorination, Methoxylation, Acetoxylation, and Cyanation of Heteroatom Organic Compounds Using Boron‐Doped Diamond, GC, and Pt Electrodes

MetadataDetails
Publication Date2023-03-24
JournalIsrael Journal of Chemistry
AuthorsHideyuki Nojima, Takashi Shimoda, Shinsuke Inagi, Toshio Fuchigami
InstitutionsTokyo Institute of Technology
Citations2

Abstract Various anodic substitution reactions such as fluorination, methoxylation, acetoxylation, and cyanation of heteroatom compounds containing a sulfur or nitrogen atom were comparatively studied using boron‐doped diamond (BDD), Pt, and glassy carbon (GC) anodes. It was found that BDD anode is highly effective for these anodic substitution reactions similarly to Pt anode although both BDD and GC electrodes are carbon‐based materials.