Multi-wavelength Raman spectroscopy of natural nanostructured carbons
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2023-08-30 |
| Journal | American Mineralogist |
| Authors | Š”. Š. ŠŃŠ°ŠµŠ½ŠŗŠ¾, Š¢. Š. ŠØŃŠ¼ŠøŠ»Š¾Š²Š°, Vladimir N. Bocharov, V. V. Ulyashev |
| Institutions | St Petersburg University, Ural Branch of the Russian Academy of Sciences |
| Citations | 4 |
Abstract
Section titled āAbstractāAbstract There is an extensive range of carbon substances with poorly ordered structures that are not well understood. Yet they are important indicators of conditions of related geological processes. The carbon minerals include nanocrystalline graphite, natural analogs of glass-like carbon (GLC)āshungite and impact ultrahigh-pressure GLC, recently discovered ultranocrystalline diamond, as well as natural carbon nanocomposites of diamond, lonsdaleite, and graphite. Studying these natural carbon substances using a standard Raman approach with excitation by visible radiation may lead to a significant distortion of the understanding of their phase states. This paper presents in detail for the first time the spectral features of natural, poorly ordered, and multiphase sp2-sp3 carbon composites by multi-wave Raman spectroscopy using laser excitations from visible to ultraviolet light applied to natural low-ordered carbon substancesānanocrystalline graphite and shungite, nanocrystalline and ultranocrystalline diamond, and multiphase carbon aggregates. The carbon state resolution advantages of ultraviolet Raman spectroscopy for phase analysis of nanostructured and poorly ordered polycomponent carbon substances containing sp2- and sp3-carbons are presented. Raman spectroscopy with ultraviolet excitation can also be applied in the analysis of industrial carbon materials, such as glassy carbon and functional carbon nanocomposites, including ultranocrystalline diamond, lonsdaleite, and amorphous sp3-carbon components.
Tech Support
Section titled āTech SupportāOriginal Source
Section titled āOriginal SourceāReferences
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