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(Invited) Preparation of N-Type and P-Type Doped Single Crystal Diamonds with Laser-Induced Doping and Microwave Plasma Chemical Vapor Deposition

MetadataDetails
Publication Date2024-05-17
JournalECS Transactions
AuthorsLinhai Guo, Tian Li, Hui Wang, Lingxue Meng, Chujun Feng
InstitutionsShanghai Advanced Research Institute, University of Chinese Academy of Sciences
Citations3

In this study, n-type doped single-crystal diamonds were successfully prepared under normal temperature and pressure conditions using laser-induced doping. 248nm pulsed laser beams with nanosecond duration were irradiated on the single crystal diamond substrate immersing in an 85% phosphoric acid solution and it introduced phosphorus doping to form an n-type doped thin layer. The resistivity of the doped region significantly decreased compared to that of the single-crystal diamond. After depositing a titanium electrode, the resistivity of the doped film obtained by Van der Pauw Technique was determined to be 1.5×10 -4 Ω·cm. Furthermore, p-type doped single-crystal diamonds were successfully prepared by introducing boron during the growth process using Microwave Plasma Chemical Vapor DepositionMPCVD. It was demonstrated that the proposed technique can introduce impurities into single crystal diamonds to form doped conductive thin layers.