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Aluminum vacancy/sulfur complex in wurtzite AlN as an optically controllable spin qubit

MetadataDetails
Publication Date2024-06-07
JournalPhysical review. B./Physical review. B
AuthorsSergey Stolbov, Marisol AlcĂĄntara Ortigoza
InstitutionsUniversity of Central Florida, Tuskegee University
Citations3

Using our rational methodology, we reveal a defect in wurtzite AlN that can serve as an optically controllable spin qubit. It combines an Al vacancy and a S atom substituting the neighboring N atom (V<sub>Al⁢</sub>S<sub>N</sub>). Linear response GW and Bethe-Salpeter equation calculations guide us to find suitable ground and excited triplet and singlet states of V<sub>Al⁢</sub>S<sub>N</sub>. The obtained optical spin-polarization cycle is similar to that observed in the negative nitrogen-vacancy (NV<sup>-</sup>) center in diamond. Furthermore, the calculated optical oscillator strengths for V<sub>Al⁢</sub>S<sub>N</sub> suggest that, in contrast to the NV<sup>-</sup> center, the optical emission in the singlet and triplet states have comparable rates, which is favorable for the qubit functionality.