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Effect of off-cut angle of hydrogen-terminated diamond(111) substrate on the quality of AlN towards high-density AlN/diamond(111) interface hole channel

MetadataDetails
Publication Date2017-01-11
JournalJournal of Applied Physics
AuthorsMasataka Imura, Ryan G. Banal, Meiyong Liao, Jiangwei Liu, T. Aizawa
InstitutionsNational Institute for Materials Science
Citations19

Single-crystal AlN/diamond heterojunction with high-density interface hole channel is successfully obtained by metal-organic vapor phase epitaxy. The AlN layer is epitaxially grown on hydrogen-terminated (H-)diamond(111) substrate. The thermal treatment of diamond substrate just before AlN growth under hydrogen and ammonia mixture environment at 1250 °C leads to surface sheet hole density as high as ∼1.0 Ɨ 1014 cmāˆ’2 without structural reconstruction of diamond surface. In addition, the use of smaller off-cut angle (0.20 ± 0.25°) H-diamond(111) substrate combined with this treatment enables to obtain single-crystal epitaxial AlN layer, which simultaneously acts as passivation of the surface hole channel with such a high density. The AlN/H-diamond(111) heterojunction reveals type-II staggered energy band configuration with valence band offset of ∼2.0 eV, which is suitable for the fabrication of p-channel field-effect transistor using AlN-gate-insulator/diamond heterojunction. These results are promising for the development of AlN/diamond hybrid power electronic devices.