Silicon anodes for lithium-ion batteries produced from recovered kerf powders
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2019-01-19 |
| Journal | Journal of Power Sources |
| Authors | Nils P. Wagner, Artur Tron, Julian R. Tolchard, Gianluigi Noia, Martin Bellmann |
| Institutions | SINTEF, Norwegian University of Science and Technology |
| Citations | 61 |
Abstract
Section titled āAbstractāSilicon kerf waste from a photovoltaic silicon production process is assessed as an anode material for application as a lithium ion battery anode. In contrast to previous studies, the Si-kerf is used as-produced, with no chemical treatment or physical processing beyond solvent PEG removal. The as-produced Si-kerf performed as well as, or better than, previously reported Si-kerf anodes and is found to outperform a cleaned Si-kerf sample from blade sawing with a larger particle size. This highlights the advantage of the diamond wire cutting process, which yields relatively small particles. In half-cell testing, a cycle life >300 cycles at a capacity of 1000 mAh gā1 is achieved with high levels of FEC addition. Full-cell testing against an NMC 442 cathode resulted in specific capacities up to 150 mAh gā1 (NMC). A relatively high degree of lithium consumption arising from repeated SEI formation is present. It is concluded that pure Si-kerf is unsuitable for commercial application in Li-ion cells.
Tech Support
Section titled āTech SupportāOriginal Source
Section titled āOriginal SourceāReferences
Section titled āReferencesā- 2001 - Issues and challenges facing rechargeable lithium batteries [Crossref]
- 2015 - Li-ion battery materials: present and future [Crossref]
- 2010 - Challenges for rechargeable Li batteriesā [Crossref]
- 2009 - Recent advances in rechargeable battery materials: a chemistās perspective [Crossref]
- 2003 - Reaction of Li with alloy thin films studied by in situ afm [Crossref]
- 2007 - Recent findings and prospects in the field of pure metals as negative electrodes for Li-ion batteries [Crossref]
- 2014 - High-capacity anode materials for lithium-ion batteries: choice of elements and structures for active particles [Crossref]
- 2012 - Size-dependent fracture of silicon nanoparticles during lithiation [Crossref]
- 2014 - High performance amorphous-Si@siox/C composite anode materials for Li-ion batteries derived from ball-milling and in situ carbonization [Crossref]
- 2004 - A vacuum deposited Si film having a Li extraction capacity over 2000 Mah/G with a long cycle life [Crossref]