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Nanomolar Quantification of Polydatin at Boron Doped Diamond Electrode. Application in Dietary Supplements

MetadataDetails
Publication Date2019-05-14
JournalInternational Journal of Electrochemical Science
AuthorsSlađana Đurđić, Vesna Vukojević, MiloÅ” Ognjanović, Bubomir Å vorc, Jelena Mutić
InstitutionsSlovak University of Technology in Bratislava, University of Belgrade
Citations4

In this research we demonstrated detailed electrochemistry polydatin. Polydatin is a natural compound with expressed antioxidant activity. Electrochemical behavior of polydatin was tested in the potential range from -1.5 V to 2 V at unmodified boron doped diamond electrode in various pH of supporting electrolyte. It has been noticed that polydatin provides two oxidation peaks, one at around 0.73 V and second at around 1.3 V. In the reverse scan no reduction peak was observed. Quantification of polydatin was done based on first oxidation peak using square wave voltammetry. After optimization of the method, linear working range from 1Ā·10-7 M to 7Ā·10-5 M was obtained, with limit of detection and limit of quantification of 6Ā·10-9 M and 2Ā·10-8 M, respectively. Negligible interferences effects were noticed. Developed method shows excellent accuracy and precision toward detection of polydatin. Also, developed method was used for quantification of polydatin in dietary supplements.