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Ultrawide-Bandgap p-n Heterojunction of Diamond/β-Ga2O3 for a Solar-Blind Photodiode

MetadataDetails
Publication Date2020-01-05
JournalECS Journal of Solid State Science and Technology
AuthorsHyun Kim, С. А. Тарелкин, A. Y. Polyakov, S. Yu. Troschiev, Sergey Nosukhin
InstitutionsKorea University, National University of Science and Technology
Citations48

The potential of ultrawide-bandgap (UWBG) semiconductors has not been fully explored because of the difficulty of forming a p-n homojunction. In this study, a mixed-dimensional UWBG p-n heterojunction composed of a p-type diamond substrate and an n-type exfoliated β -Ga 2 O 3 nanolayer has been demonstrated via a van der Waals interaction; this type of structure does not suffer from lattice mismatch. Rectifying current-voltage characteristics with a rectification ratio exceeding 10 7 were obtained with a high reverse hard breakdown voltage of 135 V. This UWBG p-n heterojunction diode exhibited good thermal stability at elevated temperatures, retaining its high rectification ratio and low reverse leakage current. Excellent photoresponse characteristics, including responsivity (12 A W −1 ), rejection ratio (8.5 × 10 3 ), photo-to-dark-current ratio (3900), and fast response/decay characteristics, were observed from the diamond/ β -Ga 2 O 3 p-n heterojunction photodiode, showing no persistent photoconductivity. The mixed-dimensional p-n heterojunction diode based on two UWBG semiconductors (p-type diamond and n-type β -Ga 2 O 3 ) can be used as a robust building block in next-generation power electronics and solar-blind optoelectronics.