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Advancement in scanning magnetic microscopy utilizing high-sensitivity room-temperature TMR sensors for geological applications

MetadataDetails
Publication Date2024-12-22
JournalEarth Planets and Space
AuthorsHirokuni Oda, Seiji Kumagai, Kosuke Fujiwara, Hitoshi Matsuzaki, Hiroshi Wagatsuma
InstitutionsTohoku University, Geological Survey of Japan
Citations2
AnalysisFull AI Review Included
  • Core Value Proposition: This research successfully demonstrates a high-sensitivity, room-temperature Scanning Magnetic Microscope (SMM) utilizing Tunnel Magneto-Resistance (TMR) sensors, offering a non-cryogenic alternative to Superconducting Quantum Interference Devices (SQUIDs) for geological applications.
  • Sensor Performance: TMR sensors (CoFeB/MgO/CoFeB-MTJs) achieved magnetic field sensitivities of approximately 30 nT/√Hz (1073 ”m sensor) and 90 nT/√Hz (357 ”m sensor) at 1 Hz after 10-point averaging.
  • Noise Reduction: The system demonstrated RMS noise levels as low as 5.87 nT in the 0.1-2.5 Hz band (10-point average), representing a factor of seven reduction compared to raw data and an order of magnitude improvement over comparable previous TMR systems.
  • Geological Validation: Magnetic maps of a vertically magnetized Hawaiian basalt thin section were consistent with reference SQUID images after computational adjustments (upward continuation and convolution) to account for TMR sensor geometry and lift-off differences (0.25 mm to 0.4 mm total distance).
  • Spatial Resolution: The TMR sensors, despite their elongated geometry (up to 1073 ”m), provided magnetic images comparable to SQUID data, validating the calibration and post-processing methods.
  • Future Goal: The practical target is achieving magnetic field sensitivity less than 5 nT with a spatial resolution of 50-200 ”m, which is necessary for ultra-fine scale magnetostratigraphic dating.
ParameterValueUnitContext
Sensor TypeTMR (MTJ)N/ACoFeB/MgO/CoFeB structure
Operating ConditionRoom TemperatureN/AEliminates cryogenic requirements
Sensor #1 Length1073”mLong sensor variant
Sensor #2 Length357”mShort sensor variant
TMR Element Width0.1”mSensing region width
TMR Element Vertical Extent100”mSensing region height
Raw Sampling Frequency50HzData acquisition rate
Sensitivity (S#1, Raw)~200nT/√Hz @ 1 HzBackground noise level
Sensitivity (S#1, 10-pt Avg)~30nT/√Hz @ 1 HzAchieved sensitivity
RMS Noise (S#1, 0.1-2.5 Hz, 10-pt Avg)5.87nTLow-frequency noise performance
Maximum Measurable Field3”TAt 100 dB amplification range
Scanning Grid Resolution0.1mmStep size for magnetic mapping
Estimated Lift-off (S#1)0.265mmDistance from sample surface
SQUID Reference Lift-off0.216mmUsed for upward continuation comparison
Target Sensitivity< 5nTDesirable for magnetostratigraphy
Target Spatial Resolution50-200”mDesirable for magnetostratigraphy
  1. System Adaptation: An existing XYZ stage and controller designed for a Scanning SQUID Microscope (SSM) were repurposed. TMR sensors were mounted in a plastic holder and placed above the sample holder within a two-layered magnetic shield.
  2. Electronics and Signal Chain: TMR sensors were connected to the analog voltage input via a DC-preamplifier (Wheatstone bridge circuit) and a DC-amplifier, utilizing a precision DC power supply (Agilent E3620A) for bias voltage.
  3. Calibration Procedure: Calibration factors (290 nT/V for S#1; 315 nT/V for S#2) were determined by measuring the magnetic field generated by a 3 mA line current and fitting the data to a theoretical infinite line current curve.
  4. Noise Characterization: Background measurements were conducted continuously at 50 Hz. Power Spectral Density (PSD) was calculated using periodograms after dividing the dataset into segments and applying a Hanning window, comparing raw data versus 10-point averaged data.
  5. Sample Measurement: A Hawaiian basalt thin section, prepared with Anhysteretic Remanent Magnetization (ARM), was scanned on a 0.1 mm grid. The stage moved at 50 mm/min, and data acquisition (0.3 s) occurred during stop-and-go steps.
  6. Drift Correction: Linear drift correction was applied by registering and averaging measurements taken at the starting (lower) and ending (upper) margins of each line scan, assuming these areas represented zero magnetic field.
  7. SSM Data Processing (Comparison): Reference SQUID magnetic images (216 ”m lift-off) were processed using Upward Continuation (using GMT grafft command) to simulate the higher lift-offs of the TMR measurements (up to 0.4 mm).
  8. Integration Simulation (Convolution): The upward-continued SQUID images were then subjected to Convolution using specific matrices (e.g., [0.5 1 1 1 0.5] for the 357 ”m sensor) to simulate the spatial integration effect caused by the elongated, serially connected TMR elements.
  • Geological and Planetary Science:
    • Submillimeter- to submicrometer-scale paleomagnetism and rock magnetism studies (e.g., volcanic rocks, meteorites).
    • Magnetostratigraphic dating of marine ferromanganese crusts and sediments, requiring high-resolution imaging of magnetic reversal boundaries.
    • Magnetic moment sensitivity measurements for single zircon crystals in paleointensity estimates.
  • Non-Destructive Evaluation (NDE) and Materials Science:
    • High-resolution mapping of magnetization and current source distributions in room-temperature samples.
    • Quality control and defect detection in magnetic materials and thin films without the complexity of cryogenic cooling.
  • Biomedical Sensing (Original Application):
    • The TMR sensors were originally developed for ultra-weak magnetic field detection, such as Magnetoencephalography (MEG), demonstrating their suitability for high-sensitivity applications.
  • Instrumentation and Microscopy:
    • Development of cost-effective, high-performance SMM systems that are simpler to operate and maintain than traditional SQUID microscopes.
View Original Abstract

Abstract Scanning magnetic microscopes enable high-sensitivity mapping of magnetic fields in thin geological sections, facilitating submillimeter- to submicrometer-scale studies of paleomagnetism and rock magnetism. Magnetic fields of geological samples have been mapped using various sensors, including Hall-effect devices, magneto-impedance devices, superconducting quantum interference devices (SQUIDs), quantum diamond devices, and tunnel magneto-resistance (TMR) devices. This study proposes magnetic microscopy using high-sensitivity room-temperature TMR sensors developed for biomagnetic applications. The goal was to create high-performance magnetic microscopes that do not require labor-intensive techniques, such as cryogenic technology. An XYZ stage developed for a scanning SQUID microscope (SSM) was used to demonstrate and evaluate magnetic microscopy with TMR sensors. The original TMR sensors developed for biomagnetic sensing composed of serially connected TMR elements with a total length of 2684 ÎŒm were shortened to 1073 ÎŒm (Sensor #1) and 357 ÎŒm length (Sensor #2). Background measurements at 50 Hz show magnetic field sensitivities better than 200 nT/√Hz and 600 nT/√Hz at 1 Hz for Sensor #1 and Sensor #2, respectively. By averaging 10 points of the original 50 Hz sampling, magnetic field sensitivities are better than 30 nT/√Hz and 90 nT/√Hz at 1 Hz for Sensor #1 and Sensor #2, respectively. To demonstrate TMR sensors as magnetic microscopes, a vertically magnetized Hawaii basalt thin section was measured and compared with a SQUID-acquired magnetic field map. Magnetic scanning images obtained with TMR sensors on a 0.1-mm grid were compared with those of SSM after adjusting the lift-off by upward continuation and integrated along the length of the sensors. The results demonstrated that magnetic images for 1073-ÎŒm-long (357 ÎŒm-long) TMR sensors aligned along the y-axis and x-axis are consistent with those after upward continuation to 0.3 mm (0.25 mm) and 0.4 mm (0.25 mm) and convolution by 1 × 10 (1 × 4) and 10 × 1 (4 × 1) matrix, respectively. Overall, the high-sensitivity TMR sensors exhibited promising performance. Further improvements can be made by optimizing the sensors, preamplifiers, and measurement systems for magnetic microscopy to achieve an optimum target resolution. Graphical Abstract

  1. 1996 - Potential theory in gravity and magnetic applications