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Determination of nitrogen spin concentration in diamond using double electron-electron resonance

MetadataDetails
Publication Date2016-07-18
JournalPhysical review. B./Physical review. B
AuthorsViktor Stepanov, Susumu Takahashi
InstitutionsUniversity of Southern California
Citations59

Diamond has been extensively investigated recently due to a wide range of potential applications of nitrogen-vacancy (NV) defect centers existing in a diamond lattice. The applications include magnetometry and quantum information technologies, and long decoherence time $({T}{2})$ of NV centers is critical for those applications. Although it has been known that ${T}{2}$ highly depends on the concentration of paramagnetic impurities in diamond, precise measurement of the impurity concentration remains challenging. In the present work we show a method to determine a wide range of the nitrogen concentration $(n)$ in diamond using a wide-band high-frequency electron spin resonance and double electron-electron resonance spectrometer. Moreover, we investigate ${T}{2}$ of the nitrogen impurities and show the relationship between ${T}{2}$ and $n$. The method developed here is applicable for various spin systems in solid and implementable in nanoscale magnetic resonance spectroscopy with NV centers to characterize the concentration of the paramagnetic spins within a microscopic volume.