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Charge-State Tuning of Single SnV Centers in Diamond

MetadataDetails
Publication Date2020-12-03
JournalACS Photonics
AuthorsTobias Lühmann, Johannes Küpper, Stefan Dietel, Robert Staacke, Jan Meijer
InstitutionsLeipzig University
Citations22

Tin-vacancy (SnV) and other group-IV vacancy centers in diamond (SiV, GeV, and PbV) are intensively studied as promising alternatives to the nitrogen-vacancy (NV) center for quantum-based applications. The knowledge and the control of their charge state are therefore major issues. Here, using p-i-p planar junctions, we explore the charge states of implanted single SnV centers. We find two classes of centers, emitting either at 620 nm (SnV-) or at 646.8 nm but not both. We demonstrate the active and reversible tuning of individual SnV- centers. However, unlike the NV centers, which we tune reversibly and continuously between NV- (638 nm), NV0 (575 nm), and NV+ (dark) states, the two kinds of SnV centers do not tune from one to the other. These findings indicate that the 646.8 nm line is likely owing to another Sn-related defect rather than to the neutral charge state of the split vacancy SnV defect along the ⟨111⟩ axis. Furthermore, p-i-p structures can be used efficiently to induce a tunable band bending, stabilize SnV- and NV- states, and explore the charge-state transition energies of many defect centers.