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Surface graphitization of diamond nanotips induced by field-emission current

MetadataDetails
Publication Date2022-04-04
JournalApplied Physics Letters
AuthorsVictor I. Kleshch, V. Porshyn, P. Serbun, Anton S. Orekhov, Р. Р. Исмагилов
InstitutionsRussian Academy of Sciences, Federal Scientific Research Centre Crystallography and Photonics
Citations13

Surface graphitization as a result of Joule heating by a field-emission (FE) current is revealed for needlelike diamond nanotips. The apex temperature and electrical resistance of the diamond needles during FE were measured by electron spectroscopy. Transmission electron microscopy indicated that the diamond structure in the near-surface layer was transformed into well-ordered graphene layers after FE with currents of up to 30 μA. The resulting structure can be viewed as a multi-walled carbon nanotube (MWCNT) having a diamond core. Thus, the observed FE behavior exhibited by the graphitized diamond needles is qualitatively similar to that of MWCNTs. On the other hand, due to its outstanding thermal conductivity, the diamond core ensures an efficient Joule heat dissipation, which provides better emission stability and higher currents, up to at least 225 μA. It makes these graphitized diamond needles promising candidates for high-brightness point electron sources required for various applications, e.g., in electron microscopy or scanning electron lithography.

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