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Tungsten Carbide Nanolayer Formation by Ion Beam Mixing with Argon and Xenon Ions for Applications as Protective Coatings

MetadataDetails
Publication Date2023-02-22
JournalACS Applied Nano Materials
AuthorsA.S. Racz, PƩter Kun, Zsolt Kerner, Zsolt Fogarassy, M. MenyhƔrd
InstitutionsHUN-REN Centre for Energy Research, Institute for Technical Physics and Materials Science
Citations8

A novel nanolayer is formed by means of ion irradiation applicable as protective coating. Tungsten carbide (WC)-rich nanolayers were produced at room temperature by applying ion beam mixing of various carbon/tungsten (C/W) multilayer structures using argon and xenon ions with energy in the range of 40-120 keV and fluences between 0.25 and 3 Ɨ 10<sup>16</sup> ions/cm<sup>2</sup>. The hardness of the nanolayers was estimated by means of standard scratch test applying an atomic force microscope equipped with a diamond-coated tip (radius < 10 nm); the applied load was 2 μN. The irradiation-induced hardness of the nanolayers correlated with the areal density of the WC; with the increasing amount of WC, the hardness of the nanolayer increased. The produced layers had an order of magnitude better corrosion resistance than a commercially available WC cermet circular saw. If the WC amount was high enough, the hardness of the layer became higher than that of the investigated WC cermet. These findings allow us to tune and design the mechanical and chemical properties of the WC protective coatings.