Skip to content

Temperature dependence of charge conversion during NV-center relaxometry in nanodiamond

MetadataDetails
Publication Date2024-04-22
JournalPhysical Review Research
AuthorsIsabel Cardoso Barbosa, Jonas Gutsche, Dennis Lönard, Stefan Dix, Artur Widera
InstitutionsUniversity of Kaiserslautern
Citations3

Temperature-dependent nitrogen-vacancy (NV)-center relaxometry is an established tool to characterize paramagnetic molecules near a sensing diamond, gaining momentum in different fields of science. However, recent results indicate that conversion between NV-center charge states impedes these measurements and influences the results for the <a:math xmlns:a=“http://www.w3.org/1998/Math/MathML”&gt;&lt;a:msub&gt;&lt;a:mi&gt;T&lt;/a:mi&gt;&lt;a:mn&gt;1&lt;/a:mn&gt;&lt;/a:msub&gt;&lt;/a:math> time. While the temperature dependence of NV centers’ <b:math xmlns:b=“http://www.w3.org/1998/Math/MathML”&gt;&lt;b:msub&gt;&lt;b:mi&gt;T&lt;/b:mi&gt;&lt;b:mn&gt;1&lt;/b:mn&gt;&lt;/b:msub&gt;&lt;/b:math> time is well studied, additional contributions from temperature-dependent charge conversion during the dark time may further affect the measurement results. We combine temperature-dependent relaxometry and fluorescence spectroscopy at varying laser powers to unravel the temperature dependence of charge conversion in nanodiamond for biologically relevant temperatures. While we observe a decrease of the <c:math xmlns:c=“http://www.w3.org/1998/Math/MathML”&gt;&lt;c:msub&gt;&lt;c:mi&gt;T&lt;/c:mi&gt;&lt;c:mn&gt;1&lt;/c:mn&gt;&lt;/c:msub&gt;&lt;/c:math> time with increasing temperatures, charge conversion remains unaffected by the temperature change. These results allow the temperature-dependent performance of <d:math xmlns:d=“http://www.w3.org/1998/Math/MathML”&gt;&lt;d:msub&gt;&lt;d:mi&gt;T&lt;/d:mi&gt;&lt;d:mn&gt;1&lt;/d:mn&gt;&lt;/d:msub&gt;&lt;/d:math> relaxometry without further consideration of temperature dependence of charge conversion. Published by the American Physical Society 2024