A2Cu3In3Te8 (A = Cd, Zn, Mn, Mg) - A Type of Thermoelectric Material with Complex Diamond-like Structure and Low Lattice Thermal Conductivities
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2019-11-20 |
| Journal | ACS Applied Energy Materials |
| Authors | Shanshan Pan, Chenyang Wang, Qidong Zhang, Bo Yang, Yan Cao |
| Institutions | Shanghai University, Southern University of Science and Technology |
| Citations | 21 |
Abstract
Section titled āAbstractāIn this work, A2Cu3In3Te8 (A = Cd, Zn, Mn, Mg) thermoelectric chalcogenide materials, exhibiting intrinsically complex structures, low lattice thermal conductivities, high Seebeck coefficients, and thus promising thermoelectric properties, are designed and explored, by a systematic complex structure search surpassing the conventional doping and carrier concentration optimizing approach. The newly introduced alloying elements A (A = Cd, Zn, Mn, Mg) are found to uniformly distribute at the 4a and 4b sites which are solely occupied by Cu and In in the cation sublattice of A2Cu3In3Te8, leading to the strong cation disordering but surprisingly stable phase. The cation disordering preserves the high structure symmetry and enhances the phonon scattering, leading to reasonably good electrical transport properties coexisting with extremely low lattice thermal conductivities (as low as ā¼0.32 W m-1 K-1 for Cd2Cu3In3Te8 at 873 K). A peak thermoelectric figure of merit zT ā¼ 0.9 at 873 K is achieved for Cd2Cu3In3Te8, which is one of the highest zT values for the pristine diamond-like compound. Also, a maximal average zT of 0.38 is obtained in the Cd2Cu3In3Te8 sample, which is 54% higher than the value of prototype CuInTe2. Our results indicate that the A2Cu3In3Te8 compound and its derivative I4-x-III4-x-A2x-VI8 (I = Cu, Ag; III = Al, Ga, In; A: divalent cations; VI = S, Se, Te; 0 < x < 4) are a promising family of thermoelectric materials with an intrinsically complex structure and low lattice thermal conductivity.